Mechanika
88(2/16), DOI: 10.7862/rm.2016.13
Intensive electro sintering of diamond composites with multicomponent Ni-Sn based binder
Roman SHMEGERA, Volodymyr KUSHCH
DOI: 10.7862/rm.2016.13
Abstract
This paper deals with intensive electro sintering (IES) of diamond composite materials (DCM) with multicomponent Ni-Sn based binder. The effect of the powder mixture composition, activating dopants and IES technical parameters on the formation of the microstructure and physical, and mechanical properties of DCM is studied. It has been established that the leading densification mechanisms of IES involve thermally activated plastic deformation of nickel powder particles, tin melting, and infiltration and chemical interaction of components. The presence of a liquid phase during the electro sintering increases conductivity of powder compact and intensity of heating which, in turn, significantly increases shrinkage rate and promotes uniform distribution of components and formation of intermetallic compounds. The macro-kinetic model of intermetallic compounds formation in the Ni-Sn system in non-isothermal conditions and the model of DCM with structured matrix and imperfect interface have been developed. The thermal and mechanical properties of electro sintered DCM have been evaluated. The initial mixture composition and the IES technological parameters promising in terms of DCM quality have been found. The proposed method of manufacturing the drilling bits by IES constitutes a potential basis for the industrial production technology of diamond tools.
References
1. Maystrenko А.L., Ivanov S.A., Pereyaslov V.P., Voloshym M.N.: Intensive electro sintering of diamond-containing composite materials, J. Superhard Materials, 22 (2000), 36-42.
2. Shmegera R.S., Kushch V.I., Maystrenko А.L.: Metal binder based on nickel for an intensive electro sintering of diamond-containing composites. J. Superhard Materials, 36 (2014) 393-400.
3. Van Beek J.A. , Stolbe S.A., van Loo F.J.J.: Multiphase diffusion in the systems Fe-Sn and Ni-Sn, Z. Metallkde, 73 (1982) 439-444.
4. Schmetterer C., Flandorfer H., Richter K.W., et al.: A new investigation of the system Ni-Sn, Intermetallics, 15 (2007) 869-884.
5. Eremenko V.N., Woodman N.D., Kostrova L.I., Verhovodov P.A.: Contact reaction at tin spreading in nickel. Powder metallurgy, 3 (1985) 31-34.
6. Bader S., Gust W., Hieber H.: Rapid formation of intermetallic compaunds by interdiffusion in the Cu-Sn and Ni-Sn systems, Acta Metall. Mater., 43 (1995) 329-337.
7. Klepser C.A.: Growth of Intermetallic Phases at Low Temperature, PhD Thesis, MIT, 1996.
8. Dybkov V.I.: Reaction Diffusion and Solid State Chemical Kinetics, IPMS Publications, Kyiv 2013p.
9. Gur D., Bamberger M.: Reactive isothermal solidification in the Ni-Sn system, Acta Materialia, 46 (1998) 4917-4923.
10. Sorokova S.N., Knyazeva A.G.: Linked model of sintering Ti-TiAl3 powder systems, Bull. Tomsk Polytechnic Univ., 314 (2009) 96-101.
11. Evstigneev N.K., Knyazeva A.G.: Choice of rheological models to describe the synthesis of the intermetallic compound, combined with extrusion through conical mold, PSTU Bulletin - Mechanics, 1 (2010) 59-71.
12. Binnewies M., Milke E.: Thermochemical Data of Elements and Compounds, Wiley, Weinheim 2002.
13. Hasselman, D.P.H. and Johnson, L.F.: Effective thermal conductivity of composites with interfacial thermal barrier resistance, J. Compos. Mater., 21 (1987) 508-515.
14. Shmegera R.S., Podoba Ya.O., Kushch V.I., Belyaev A.S.: Effect of the contact conductivity of the diamond-metal binder interface on the thermal conductivity of diamond-containing composites, J. Superhard Materials, 37 (2015) 242-252.
15. Stoner R.J., Maris H.J., Anthony T.R., Banholzer W.F.: Measurements of the Kapitza conductance between diamond and several metals, Phys. Rev. Let., 68 (1992) 1563-1566.
16. Kushch V.I., Dub S.N., Shmegera R.S., Sirota Yu.V., Tolmacheva G.N.: Procedure of the multiple indentations for determination of the hardness parameters of heterogeneous materials J. Superhard Materials, 37 (2015) 173-181.
17. Bokhonov B.B.,Ukhina A.V., Dudina D.V., Gerasimov K.B., Anisimov A.G., Mali V.I.: Towards a better understanding of nickel/diamond interactions: the interface formation at low temperatures, RSC Advances, 5 (2015) 51799-51806.
About this Article
TITLE:
Intensive electro sintering of diamond composites with multicomponent Ni-Sn based binder
AUTHORS:
Roman SHMEGERA (1)
Volodymyr KUSHCH (2)
AUTHORS AFFILIATIONS:
(1) V. Bakul Institute for Superhard Materials of the National Academy of Sciences, Kyiv, Ukraine
(2) V. Bakul Institute for Superhard Materials of the National Academy of Sciences, Kyiv, Ukraine
JOURNAL:
Mechanika
88(2/16)
KEY WORDS AND PHRASES:
diamond composites, shrinkage, sintering, thermal conductivity
FULL TEXT:
http://doi.prz.edu.pl/pl/pdf/mechanika/177
DOI:
10.7862/rm.2016.13
URL:
http://dx.doi.org/10.7862/rm.2016.13
RECEIVED:
2016-05-12
ACCEPTED:
2016-06-22
COPYRIGHT:
Publishing House of Rzeszow University of Technology Powstańców Warszawy 12, 35-959 Rzeszow